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[Bis(trifluoroacetoxy)iodo]benzene, 97%, Thermo Scientific Chemicals Product Code.: 11368166
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[Bis(trifluoroacetoxy)iodo]benzene, 97%, Thermo Scientific Chemicals

Product Code. 11368166
5 g
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Quantity:
5 g
25 g
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Product Code. 11368166

Brand: Thermo Scientific Alfa Aesar L15141.06

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Description

[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Solubility
Insoluble in water.

Notes
Light and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases.
TRUSTED_SUSTAINABILITY

Identificatori chimici

CAS 2712-78-9
Molecular Formula C10H5F6IO4
Molecular Weight (g/mol) 430.041
MDL Number MFCD00009672
InChI Key PEZNEXFPRSOYPL-UHFFFAOYSA-N
Synonym bis trifluoroacetoxy iodo benzene, pifa, unii-659sfv27xs, bis-trifluoroacetoxyiodobenzene, phenylbis trifluoroacetato-o iodine, bis i,i-trifluoroacetoxy iodobenzene, iodine, phenylbis trifluoroacetato-o, bis trifluoracetoxy-iodobenzene, bis trifluoroacetoxy phenyl iodaneShow MoreShow Less
PubChem CID 102317
IUPAC Name [phenyl-(2,2,2-trifluoroacetyl)oxy-$l^{3}-iodanyl] 2,2,2-trifluoroacetate
SMILES C1=CC=C(C=C1)I(OC(=O)C(F)(F)F)OC(=O)C(F)(F)F

Specifica

Melting Point 122°C to 125°C
Quantity 5 g
Beilstein 764767
Sensitivity Light and moisture sensitive
Solubility Information Insoluble in water.
Formula Weight 430.04
Percent Purity 97%
Chemical Name or Material [Bis(trifluoroacetoxy)iodo]benzene

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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10226935 Certificate TypeCertificate of Analysis Date30/08/2024 Catalog NumberL15141.06,L15141.14
Lot Number10240976 Certificate TypeCertificate of Analysis Date10/06/2022 Catalog NumberL15141.06,L15141.14
Lot Number10036795 Certificate TypeCertificate of Analysis Date08/12/2021 Catalog NumberL15141.06,L15141.14
Lot Number10193001 Certificate TypeCertificate of Analysis Date08/12/2021 Catalog NumberL15141.06,L15141.14
Lot Number10199397 Certificate TypeCertificate of Analysis Date08/12/2021 Catalog NumberL15141.06,L15141.14

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