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Ethyl bromoacetate, 98%, Thermo Scientific Chemicals Product Code.: 11448663
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Ethyl bromoacetate, 98%, Thermo Scientific Chemicals

Product Code. 11448663
100 g
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Product Code. 11448663

Brand: Thermo Scientific Alfa Aesar A10448.22

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Description

Ethyl bromoacetate is widely used as an alkylating reagent involved in the Reformatsky reaction to prepare the beta-hydroxy esters by reacting with carbonyl compounds. It is also used for the syntheses of witting reagent, artificial diethylstilbestrol antigen, 3-phenyl-1-naphthol and steroidal thiazolidinone derivatives. It finds applications in the preparation of reversibly photoresponsive coumarin-stabilized polymeric nanoparticles in an aqueous medium which act as a detectable drug carrier.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethyl bromoacetate is widely used as an alkylating reagent involved in the Reformatsky reaction to prepare the beta-hydroxy esters by reacting with carbonyl compounds. It is also used for the syntheses of witting reagent, artificial diethylstilbestrol antigen, 3-phenyl-1-naphthol and steroidal thiazolidinone derivatives. It finds applications in the preparation of reversibly photoresponsive coumarin-stabilized polymeric nanoparticles in an aqueous medium which act as a detectable drug carrier.

Solubility
Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water.

Notes
It is a lachrymator. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 105-36-2
Molecular Formula C4H7BrO2
Molecular Weight (g/mol) 167.002
MDL Number MFCD00000191
InChI Key PQJJJMRNHATNKG-UHFFFAOYSA-N
Synonym ethyl bromoacetate, antol, ethyl bromacetate, bromoacetic acid ethyl ester, ethyl monobromoacetate, acetic acid, bromo-, ethyl ester, ethoxycarbonylmethyl bromide, bromoacetic acid, ethyl ester, ethyl alpha-bromoacetate, ethyl bromo acetateShow MoreShow Less
PubChem CID 7748
IUPAC Name ethyl 2-bromoacetate
SMILES CCOC(=O)CBr

Specifications

Melting Point °C to 38°C
Density 1.506 g/mL
Boiling Point 159°C
Flash Point 47°C (117°F)
Assay Percent Range 98%
Linear Formula BrCH2CO2CH2CH3
Refractive Index 1.451
Quantity 100 g
UN Number UN1603
Solubility Information Miscible with ethanol,acetone,benzene and ethyl ether. Immiscible with water.
Formula Weight 167
Percent Purity 98%
Chemical Name or Material Ethyl bromoacetate
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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10238920 Certificate TypeCertificate of Analysis Date30/08/2024 Catalog NumberA10448.22,A10448.0E,A10448.36
Lot Number10249328 Certificate TypeCertificate of Analysis Date25/01/2024 Catalog NumberA10448.22,A10448.0E,A10448.36
Lot Number10248110 Certificate TypeCertificate of Analysis Date26/09/2023 Catalog NumberA10448.22,A10448.0E,A10448.36
Lot Number10244964 Certificate TypeCertificate of Analysis Date07/12/2022 Catalog NumberA10448.22,A10448.0E,A10448.36
Lot NumberH5638C Certificate TypeCertificate of Analysis Date22/11/2021 Catalog NumberA10448.22,A10448.0E,A10448.36

Safety and Handling

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Product Identifier
  • Ethyl bromoacetate
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 1
  • Acute toxicity Category 2
  • Flammable liquid Category 3
 Hazard Statement
  • H226-Flammable liquid and vapour.
  • H300-Fatal if swallowed.
  • H310-Fatal in contact with skin.
  • H330-Fatal if inhaled.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P310-Immediately call a POISON CENTER/doctor/.
  • P330-Rinse mouth.
 Supplemental information
  • MIXTURE LIST-Contains : Ethyl bromoacetate
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